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Trimethyl sulfoxide iodide

Trimethylsulfoxonium iodide

CAS: 1774-47-6

Molecular Formula: C3H9IOS

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Trimethyl sulfoxide iodide - Names and Identifiers

Name Trimethylsulfoxonium iodide
Synonyms trimethyl-sulfoxoniuiodide
Trimethyl sulfoxide iodide
rimethylsulfoxonium iodide
Trimethylsulfoxonium iodide
Trimethylsulphoxonium iodide
Tri methyl sulfoxonium iodide
Sulfoxonium,trimethyl-,iodide
Trimethyl(oxo)-sulfanylium iodide
sulfonium,trimethyl-,iodide,oxide
CAS 1774-47-6
EINECS 217-204-2
InChI InChI=1/C3H9OS.HI/c1-5(2,3)4;/h1-3H3;1H/q+1;/p-1
InChIKey BPLKQGGAXWRFOE-UHFFFAOYSA-M

Trimethyl sulfoxide iodide - Physico-chemical Properties

Molecular FormulaC3H9IOS
Molar Mass220.07
Density1.7074 (estimate)
Melting Point208-212 °C (dec.) (lit.)
Water Solubility15 g/L (20 ºC)
Solubility H2O: 50mg/mL, clear
AppearanceWhite solid
ColorWhite to light yellow
BRN3595854
PHpH(50g/l, 25℃) : 4.8～6.0
Storage ConditionKeep in dark place,Inert atmosphere,Room temperature
SensitiveLight Sensitive
MDLMFCD00011899

Trimethyl sulfoxide iodide - Risk and Safety

Risk CodesR36/37/38 - Irritating to eyes, respiratory system and skin.
R22 - Harmful if swallowed
Safety DescriptionS37/39 - Wear suitable gloves and eye/face protection
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
S24/25 - Avoid contact with skin and eyes.
WGK Germany2
RTECSWS3585000
FLUKA BRAND F CODES8
TSCAYes
HS Code29309070

Trimethyl sulfoxide iodide - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
Properties Trimethylsulfoxide iodide is a white to light yellow crystal, soluble in water and dimethyl sulfoxide, slightly soluble in methanol.
Use Trimethylsulfoxide iodide is used to synthesize methylene transfer reagents for the preparation of epoxy compounds.
It is mainly used to synthesize fluconazole.
Strong alkali treatment can generate endonium salt, which can react with the carbonyl group of ketones and aldehydes to form epoxides; it can also preferentially react with the double bonds of α,β-unsaturated esters to generate cyclopropyl ester
Last Update：2024-04-10 22:29:15
Trimethyl sulfoxide iodide
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View History
Trimethyl sulfoxide iodide
ETHYL QUINOL
TERT-BUTYL 7-AMINOHEPTYLCARBAMATE
3-METHYL-BUT-2-ENOYL CHLORIDE
dodecyl phenyl ammonium sulfate
ANTISTATIC AGENT
T56 BMNJ FE HG
ETHYLACETYL-L-TYROSINE
SODIUM 4-AMINOSALICYLATE DIHYDRATE
BORN TRIFLUORIDE-METHANOL COMPLEX
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